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Solar fuel from photo-thermal catalytic reactions with spectrum-selectivity: a review

Sanli TANG, Jie SUN, Hui HONG, Qibin LIU

Frontiers in Energy 2017, Volume 11, Issue 4,   Pages 437-451 doi: 10.1007/s11708-017-0509-z

Abstract: This paper reviews different approaches for solar fuel production from spectrum-selective photo-thermalsynergetic catalysis.review begins with the meaning of synergetic effects, and the mechanisms of spectrum-selectivity and photo-thermalcatalysis.A discussion is finally presented concerning future development of photo-thermal catalytic reactions

Keywords: photo-thermal catalysis     spectrum-selectivity     solar fuel     full-spectrum    

Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

Frontiers in Energy 2018, Volume 12, Issue 1,   Pages 43-71 doi: 10.1007/s11708-018-0524-8

Abstract: light by electrons or individual functional groups within molecules leads to changes in the sample’s thermalFor example, photothermal induced resonance (PTIR) spectroscopy methods measure a sample’s local thermalTherefore, they use the AFM tip as a thermal detector to directly relate absorbed IR light to the thermalMore recently, photo-induced force microscopy (PiFM) has been developed to measure the change of the

Keywords: vibrational spectroscopy     atomic force microscopy     photo-thermal induced resonance     scanning near-fieldoptical microscopy     tip-enhanced Raman spectroscopy     photo-induced force microscopy     molecular resonances    

Lignin-based electrospun nanofiber membrane decorated with photo-Fenton Ag@MIF-100(Fe) heterojunctions

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7,   Pages 930-941 doi: 10.1007/s11705-023-2309-9

Abstract: /i> seeding method to fabricate a lignin-based electrospun nanofiber membrane (LENM) decorated with photo-Fentonwithin 30 min under illumination, which is attributed to a synergy of dye adsorption/enrichment and photo-FentonTherefore, the lignin-based photo-Fenton hybrid membrane can lay the foundation for the preparation and

Keywords: lignin     electrospinning     heterojunctions     photo-Fenton catalysis     wastewater remediation    

Plasma-catalysis: Is it just a question of scale?

J. Christopher Whitehead

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 2,   Pages 264-273 doi: 10.1007/s11705-019-1794-3

Abstract: The focus is on non-thermal plasma where the lack of thermal equilibrium creates a range of temperatureIt is concluded that plasma-catalysis is best regarded as conventional catalysis perturbed by the presenceThe sometimes used description “plasma-activated catalysis” is an apt one.

Keywords: plasma catalysis     plasma-activated catalysis     non-thermal plasma     CO2 conversion    

The CatMath: an online predictive platform for thermal + electrocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 2156-2160 doi: 10.1007/s11705-023-2371-3

Abstract: activity models are the quantified and visualized tools of the Sabatier principle for heterogeneous catalysisintroduce the CatMath—an online platform for generating a variety of common and industrially important thermal

Keywords: CatMath     catalysis     volcano activity plots     Surface Pourbaix Diagrams     online platform    

Efficient degradation of orange II by ZnMn

Qingzhuo Ni, Hao Cheng, Jianfeng Ma, Yong Kong, Sridhar Komarneni

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 956-966 doi: 10.1007/s11705-019-1907-z

Abstract: ., the photocatalysis system with visible light, the chemocatalysis system with bisulfite, and the photo-chemicalcatalysis system with both visible light and bisulfite.O , h , e , SO and HO are proposed to be responsible for the excellent degradation results in the photo-chemicalcatalysis system with the ZnMn O catalyst.

Keywords: ZnMn2O4     photo-chemical catalysis     bisulfite     dye degradation    

Experimental and computational assessment of 1,4-Dioxane degradation in a photo-Fenton reactive ceramic

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 5, doi: 10.1007/s11783-020-1341-y

Abstract:

• 1,4-Dioxane was degraded via the photo-Fenton reactive membrane filtration

Keywords: Photo-Fenton     Ceramic membrane     1     4-Dioxane     Goethite    

Selective reduction of NO by photo-SCR with ammonia in an annular fixed-film photoreactor

YiangChen CHOU, Young KU

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 2,   Pages 149-155 doi: 10.1007/s11783-010-0296-9

Abstract: Gaseous NO was photocatalytically reduced at room temperature by photo-assisted selective catalytic reduction(photo-SCR) with ammonia over TiO in this study.The kinetic model proposed in this study can be used to reasonably describe the reaction mechanism of photo-SCR

Keywords: photo-SCR     photocatalysis     NO reduction     Eley-Rideal model    

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 12,   Pages 1879-1894 doi: 10.1007/s11705-023-2354-4

Abstract: In this review, we systematically discussed the halogen-free catalysis for cycloaddition of CO2<

Keywords: carbon dioxide     halogen-free catalysis     cyclic carbonate     mechanistic insight    

Hypoxia-induced activity loss of a photo-responsive microtubule inhibitor azobenzene combretastatin A4

Yang An, Chao Chen, Jundong Zhu, Pankaj Dwivedi, Yanjun Zhao, Zheng Wang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 5,   Pages 880-888 doi: 10.1007/s11705-019-1864-6

Abstract: The conformation-dependent activity of azobenzene combretastatin A4 (Azo-CA4) provides a unique approach to reduce the side-effects of chemotherapy, due to the light-triggered conformation transition of its azobenzene moiety. Under hypoxic tumor microenvironment, however, the high expression of azoreductase can reduce azobenzene to aniline. It was postulated that the Azo-CA4 might be degraded under hypoxia, resulting in the decrease of its anti-tumor activity. The aim of this study was to verify such hypothesis in HeLa cells . The quantitative drug concentration analysis shows the ratiometric formation of degradation end-products, confirming the bioreduction of Azo-CA4. The tubulin staining study indicates that Azo-CA4 loses the potency of switching off microtubule dynamics under hypoxia. Furthermore, the cell cycle analysis shows that the ability of Azo-CA4 to induce mitotic arrest is lost at low oxygen content. Therefore, the cytotoxicity of Azo-CA4 is compromised under hypoxia. In contrast, combretastatin A4 as a positive control maintains the potency to inhibit tubulin polymerization and break down the nuclei irrespective of light irradiation and oxygen level. This work highlights the influence of hypoxic tumor microenvironment on the anti-tumor potency of Azo-CA4, which should be considered during the early stage of designing translational Azo-CA4 delivery systems.

Keywords: hypoxia     microtubule inhibitor     drug delivery     azo-combretastatin A4     photo-responsive    

Application of heterogeneous catalysis to biodiesel synthesis using microalgae oil

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 5, doi: 10.1007/s11783-020-1343-9

Abstract:

• Microalgae oil application for biodiesel synthesis is discussed.

Keywords: Biodiesel     Heterogeneous catalysis     Transesterification     Microalgae oil    

Frontiers of Catalysis Chemistry and Technology

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 1-2 doi: 10.1007/s11705-018-1704-0

Scaling up of cluster beam deposition technology for catalysis application

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1360-1379 doi: 10.1007/s11705-021-2101-7

Abstract: the low throughput of the physical synthesis method has severely constrained its wider adoption for catalysis

Keywords: nanoparticle     cluster     cluster beam deposition     magnetron sputtering     heterogeneous catalysis    

Preface to special issue on “Advanced Materials and Catalysis

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1357-1359 doi: 10.1007/s11705-021-2119-x

Cyanobacterial photo-driven mixotrophic metabolism and its advantages for biosynthesis

Ni Wan,Mary Abernathy,Joseph Kuo-Hsiang Tang,Yinjie J. Tang,Le You

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 3,   Pages 308-316 doi: 10.1007/s11705-015-1521-7

Abstract: The photo-fermentations show enhanced photosynthesis, while CO loss from organic substrate degradationThe use of cyanobacteria as “green ” could be a promising route to develop robust photo-biorefineries

Keywords: CO2 mass transfer     N2 fixation     photosystem     RuBisCO     the TCA cycle    

Title Author Date Type Operation

Solar fuel from photo-thermal catalytic reactions with spectrum-selectivity: a review

Sanli TANG, Jie SUN, Hui HONG, Qibin LIU

Journal Article

Review: Tip-based vibrational spectroscopy for nanoscale analysis of emerging energy materials

Amun JARZEMBSKI, Cedric SHASKEY, Keunhan PARK

Journal Article

Lignin-based electrospun nanofiber membrane decorated with photo-Fenton Ag@MIF-100(Fe) heterojunctions

Journal Article

Plasma-catalysis: Is it just a question of scale?

J. Christopher Whitehead

Journal Article

The CatMath: an online predictive platform for thermal + electrocatalysis

Journal Article

Efficient degradation of orange II by ZnMn

Qingzhuo Ni, Hao Cheng, Jianfeng Ma, Yong Kong, Sridhar Komarneni

Journal Article

Experimental and computational assessment of 1,4-Dioxane degradation in a photo-Fenton reactive ceramic

Journal Article

Selective reduction of NO by photo-SCR with ammonia in an annular fixed-film photoreactor

YiangChen CHOU, Young KU

Journal Article

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

Journal Article

Hypoxia-induced activity loss of a photo-responsive microtubule inhibitor azobenzene combretastatin A4

Yang An, Chao Chen, Jundong Zhu, Pankaj Dwivedi, Yanjun Zhao, Zheng Wang

Journal Article

Application of heterogeneous catalysis to biodiesel synthesis using microalgae oil

Journal Article

Frontiers of Catalysis Chemistry and Technology

Journal Article

Scaling up of cluster beam deposition technology for catalysis application

Journal Article

Preface to special issue on “Advanced Materials and Catalysis

Journal Article

Cyanobacterial photo-driven mixotrophic metabolism and its advantages for biosynthesis

Ni Wan,Mary Abernathy,Joseph Kuo-Hsiang Tang,Yinjie J. Tang,Le You

Journal Article